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SELECTION OF POUR POINT DEPRESSANTS FOR TODAYS ENGINE OILS INCLUDING AGING IN THE PRESENCE OF BIODIESEL BY CEC L-105

机译:CEC L-105用于当今包括机油老化的发动机油中的点滴抑制剂的选择

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摘要

All mineral derived base stocks used in lubricants contain waxy hydrocarbons that come out of solution when temperature decreases. They can form a three-dimensional wax crystal network that can totally immobilise the oil. In formulated engine oils some additives have a “waxy” or crystalline structure and further contribute to the formation of a crystal network that impairs oil flow. Waxiness is evidenced at low temperature by higher pour-point, yield stress and viscosity compared to a wax free oil. Inadequate oil flow to critical parts of the equipment may result in costly failures. The function of Pour-Point Depressant (PPD) is given in the name. They depress pour-point by inhibiting the waxy structures that form in mineral oil at low temperature. But for modern engine oils pour-point has little relevance and isn’t included in modern international engine oil standards. Industry experience over the decades has replaced pour-point by other more valid assessments of an engine oil’s suitability at low temperature. In particular low temperature pumpability by Mini Rotary Viscometer (MRV) due to its inclusion in SAE J300 specification is the primary test. In some cases this is now required on used oil, and most recently in Europe on oil oxidised in the presence of biodiesel by CEC-L-105-12. However PPDs exist or have been developed which are effective in these evolved low temperature requirements of engine oils.In this paper we show that PPDs are available which are effective against this latest European CEC L-105 requirement, although extra consideration must be given to their selection. We also show that multiple low temperature requirements tend to narrow the choice of acceptable PPDs, and the choice of PPD can be strongly influenced by the presence of other additives in addition to the mineral oil. These combined with the extra requirement for CEC L-105 has made PPD selection more difficult, but based on our work reported here this new challenge can be met by correct PPD selection.
机译:润滑剂中使用的所有矿物衍生基础油都包含蜡状烃,当温度降低时,蜡状烃会从溶液中析出。它们可以形成可以完全固定油的三维蜡晶网络。在配制的发动机油中,某些添加剂具有“蜡状”或晶体结构,并进一步有助于形成损害油流的晶体网络。与不含蜡的油相比,在更高的倾点,屈服应力和粘度下,蜡质在低温下得到证明。没有足够的油流到设备的关键部件,可能会导致代价高昂的故障。名称中给出了降凝剂(PPD)的功能。它们通过抑制矿物油在低温下形成的蜡状结构来降低倾点。但是,对于现代机油而言,倾点几乎没有任何意义,也不包含在现代国际机油标准中。数十年来的行业经验已经用其他更有效的评估机油在低温下适用性的方法代替了倾点。尤其是由于微型旋转粘度计(MRV)包含在SAE J300规范中,因此具有低温抽运性,这是主要测试。在某些情况下,现在对废油是必需的,最近在欧洲,对于在存在生物柴油的情况下被CEC-L-105-12氧化的油来说,这是必需的。然而,存在或已经开发出可有效满足这些不断发展的发动机油低温要求的PPD。在本文中,我们证明了可以使用的PPD可以有效地满足最新的欧洲CEC L-105要求,尽管必须格外考虑选择。我们还表明,多种低温要求往往会缩小可接受的PPD的选择范围,而且除矿物油外,其他添加剂的存在也会严重影响PPD的选择。这些加上CEC L-105的额外要求,使得PPD的选择更加困难,但是根据我们在此报告的工作,正确的PPD选择可以解决这一新挑战。

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